Crystal structure of aqua [N,N¢-bis(3-methoxysalicylidene)propane-1,2- diaminato]methanolmanganese(III) perchlorate

Abstract

The title compound, a hydrogen-bonded pseudo-dimer, Mn(C19H18N2O4)(CH4O)(H2O)]ClO4, (I), has been structurally characterized. Complex (I) affords an elongated octahedral coordination environment, with axial Mn-O(CH3OH) = 2.296(5) and Mn-O(water) = 2.208(3)Å.