Crystal structure and magnetic characterization of mu(6)-oxo bridged hexanuclear Fe(III) complex

dc.authorid0000-0003-3488-5284en_US
dc.contributor.authorKara, Hülya
dc.contributor.authorGüngör, Elif
dc.contributor.authorÇoban, Mustafa Burak
dc.contributor.authorAcar, Yasemin
dc.date.accessioned2020-01-23T12:58:36Z
dc.date.available2020-01-23T12:58:36Z
dc.date.issued2019en_US
dc.departmentFakülteler, Fen-Edebiyat Fakültesi, Fizik Bölümüen_US
dc.departmentRektörlüğe Bağlı Bölümler, Araştırma ve Uygulama Merkezleri, Bilim ve Teknoloji Uygulama ve Araştırma Merkezien_US
dc.descriptionGüngör, Elif (Balikesir Author)en_US
dc.description.abstractIn this study, the synthesis, X-ray crystal structure and magnetic properties of a new hexanuclear Fe(III) complex, 2[OFe6(thme)(4)Cl-6].4[C6H15N].6[H2O] (1), (H(3)thme = 1,1,1-Tris(hydroxymethyl)ethane) is reported. The structure of 1 is described as the hexametalate core [OFe6(thme)(4)Cl-6] consisting of an octahedral arrangement by four alkoxo oxygen atom from thme ligand, a terminal chloride atom and one mu(6)-oxo group at the center. Variable-temperature magnetic susceptibility measurements of 1 indicate an antiferromagnetic interaction between the Fe(III) centers.en_US
dc.identifier.doi10.1016/j.inoche.2019.107466
dc.identifier.endpageyoken_US
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.issueyoken_US
dc.identifier.startpageyoken_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2019.107466
dc.identifier.urihttps://hdl.handle.net/20.500.12462/10553
dc.identifier.volume107en_US
dc.identifier.wosWOS:000487570600021
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHexanuclear Iron Clusteren_US
dc.subjectCrystal Structureen_US
dc.subjectAntiferromagnetic Interactionen_US
dc.titleCrystal structure and magnetic characterization of mu(6)-oxo bridged hexanuclear Fe(III) complexen_US
dc.typeArticleen_US

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