Ring-opening mechanism of lithium bromosilacyclopropylidenoids to silaallenes
| dc.authorid | 0000-0002-0424-4673 | en_US |
| dc.authorid | 0000-0002-5098-1842 | en_US |
| dc.contributor.author | Azizoğlu, Akın | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.date.accessioned | 2019-10-16T10:53:50Z | |
| dc.date.available | 2019-10-16T10:53:50Z | |
| dc.date.issued | 2010 | en_US |
| dc.department | Fakülteler, Fen-Edebiyat Fakültesi, Kimya Bölümü | en_US |
| dc.description | Azizoğlu, Akın (Balikesir Author) | en_US |
| dc.description.abstract | Density functional theory and ab initio quantum mechanical calculations elucidated the ring opening reactions of 1 bromo 1 lithiosilirane (3) and 2 bromo 2 lithiosilirane (4) to 2 silallene (6) and 1 silaallene (7) respectively The ring opening of 3 to 6 can proceed in a stepwise fashion with the intermediacy of a free silacyclopropylidene (9) Here a high energy barrier needs to be overcome in order to open the silacyclopropylidene ring and to generate 6 On the contrary the ring opening of 4 to 7 can occur in a concerted fashion | en_US |
| dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK) | en_US |
| dc.identifier.doi | 10.1021/om100868b | |
| dc.identifier.endpage | 6743 | en_US |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.issue | 24 | en_US |
| dc.identifier.scopus | 2-s2.0-78650670915 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 6739 | en_US |
| dc.identifier.uri | https://doi.org/10.1021/om100868b | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12462/6921 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wos | WOS:000285373100017 | |
| dc.identifier.wosquality | Q1 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | en_US |
| dc.publisher | Amer Chemıcal Soc | en_US |
| dc.relation.ispartof | Organometallıcs | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/embargoedAccess | en_US |
| dc.title | Ring-opening mechanism of lithium bromosilacyclopropylidenoids to silaallenes | en_US |
| dc.type | Article | en_US |
