Cyanide-bridged trinuclear Mn-III-Fe-III assembly: Crystal structure, magnetic and photoluminescence behavior
| dc.authorid | 0000-0003-3488-5284 | en_US |
| dc.contributor.author | Erkarslan, Uğur | |
| dc.contributor.author | Oylumluoğlu, Görkem | |
| dc.contributor.author | Çoban, Mustafa Burak | |
| dc.contributor.author | Öztürk, Esra | |
| dc.contributor.author | Kara, Hülya | |
| dc.date.accessioned | 2019-10-17T11:45:36Z | |
| dc.date.available | 2019-10-17T11:45:36Z | |
| dc.date.issued | 2016 | en_US |
| dc.department | Fakülteler, Fen-Edebiyat Fakültesi, Fizik Bölümü | en_US |
| dc.department | Rektörlüğe Bağlı Bölümler, Araştırma ve Uygulama Merkezleri, Bilim ve Teknoloji Uygulama ve Araştırma Merkezi | en_US |
| dc.description | Çoban, Mustafa Burak (Balikesir Author) | en_US |
| dc.description.abstract | A trinuclear cyanide-bridged Mn-III-Fe-III compound, [NEt4][Mn(3,5-ClL)(2)(MeOH)](2)Fe(CN)(6)], [3,5-ClLH2 = N, N'-bis(3,5-chlorosalicylidenato)-1,2-diamino propane)], 1, has been characterized by X-ray analyses, magnetic and photoluminescence measurements. The structure assumes a two-dimensional network consisting of Mn-NC-Fe-CN-Mn (Fe1-C19-N4 = 175.9(3)degrees, C19-N4-Mn1 = 145.5 (3)degrees). The magnetic properties of this compound indicate antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridges. Furthermore, solid state photoluminescence properties of complex 1 have been investigated at room temperature. | en_US |
| dc.identifier.doi | 10.1016/j.ica.2016.02.010 | |
| dc.identifier.endpage | 61 | en_US |
| dc.identifier.issn | 1873-3255 | |
| dc.identifier.issn | 0020-1693 | |
| dc.identifier.scopus | 2-s2.0-84966664873 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 57 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.ica.2016.02.010 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12462/8733 | |
| dc.identifier.volume | 445 | en_US |
| dc.identifier.wos | WOS:000372747600008 | |
| dc.identifier.wosquality | Q2 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Sci Ltd | en_US |
| dc.relation.ispartof | Inorganica Chimica Acta | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.relation.tubitak | info:eu-repo/grantAgreement/TUBITAK/TBAG-108T431 | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Magnetism | en_US |
| dc.subject | Photoluminescence | en_US |
| dc.subject | X-ray Analyses | en_US |
| dc.subject | Cyano-Bridged | en_US |
| dc.subject | Mn-III-Fe-III Compound | en_US |
| dc.title | Cyanide-bridged trinuclear Mn-III-Fe-III assembly: Crystal structure, magnetic and photoluminescence behavior | en_US |
| dc.type | Article | en_US |
