Phase transition and luminescence characteristics of dysprosium doped strontium stannate phosphor synthesized using hydrothermal method

Abstract

A series of strontium stannate (SrSnO3) doped with Dy3+ ions at various wt % concentrations (1, 2, 3 and 5) were synthesized via hydrothermal reaction and analysed using X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), environmental electron scanning microscope (ESEM), photoluminescence (PL) and, cathodoluminescence (CL). The XRD results confirmed that all samples were assigned to cubic perovskite-type SrSnO3 structured with the Pm3m space group. The PL emission spectrum of Dy3+ activated samples consisted of some characteristic peaks located at 481 nm, 572 nm, 660 nm and 753 nm, corresponding to ( 4 F9/2 → 6 H15/2, blue), ( 4 F9/2 → 6 H13/2, yellow), 660 nm ( 4 F9/2 → 6 H11/2, red) and 753 nm ( 4 F9/2 → 6 H9/2, red) transitions. The PL emission line intensity is gradually enhanced with an increase in doping concentration up to 3 wt %, followed by concentration quenching. The confinement effects of localized resonant energy transfer might cause higher concentration quenching. PL emission spectra were affected by the temperature range from 10 K to 300 K. PL emission anomalies at 270 K in SrSnO3:Dy3+ have been reported to be consistent with a structural phase transition at this temperature. This work confirms Singh et al.’s observation, revealing that SrSnO3 has a phase transition at 270 K.