Chiral one-dimensional hydrogen bonded, antiferromagnetic chloro-bridged dinuclear copper(II) complex with tridentate Schiff base ligand
| dc.contributor.author | Güngör, Elif | |
| dc.contributor.author | Kara, Hülya | |
| dc.date.accessioned | 2019-10-17T11:57:57Z | |
| dc.date.available | 2019-10-17T11:57:57Z | |
| dc.date.issued | 2012 | en_US |
| dc.department | Fakülteler, Fen-Edebiyat Fakültesi, Fizik Bölümü | en_US |
| dc.description.abstract | Chiral one-dimensional hydrogen bonded copper(II) complex [Cu(HL1)Cl](2)center dot H2O (1) (HL1 = N-(2-hydroxyethyl)-5-nitrosalicylaldimine) has been synthesized and characterized by elemental analysis, crystal structure analysis and magnetic susceptibility. X-ray diffraction studies show that 1 is a binuclear copper(II) complex with a pair of chlorine atoms bridging the copper atoms in a central Cu2Cl2 core. Each copper(II) atom is five-coordinated in a square-pyramidal environment. Variable-temperature magnetic susceptibility measurements on the a binuclear complex 1 in the range 2-300 K indicate a weak antiferromagnetic coupling between the binuclear copper(II) centers, with J = -0.274 cm(-1) and the magneto-structural correlations are discussed in detail. | en_US |
| dc.description.sponsorship | Balikesir University - BAP-2010/33 Nato-B1-TUBITAK | en_US |
| dc.identifier.doi | 10.1016/j.ica.2011.11.047 | |
| dc.identifier.endpage | 142 | en_US |
| dc.identifier.issn | 0020-1693 | |
| dc.identifier.scopus | 2-s2.0-84857914253 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 137 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.ica.2011.11.047 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12462/8838 | |
| dc.identifier.volume | 384 | en_US |
| dc.identifier.wos | WOS:000301179600019 | |
| dc.identifier.wosquality | Q2 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science | en_US |
| dc.relation.ispartof | Inorganica Chimica Acta | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.relation.tubitak | info:eu-repo/grantAgreement/TUBITAK/108T431 | en_US |
| dc.rights | info:eu-repo/semantics/embargoedAccess | en_US |
| dc.subject | Schiff Base | en_US |
| dc.subject | Copper(II) Complex | en_US |
| dc.subject | X-Ray Crystal Structures | en_US |
| dc.subject | Magnetic Properties | en_US |
| dc.title | Chiral one-dimensional hydrogen bonded, antiferromagnetic chloro-bridged dinuclear copper(II) complex with tridentate Schiff base ligand | en_US |
| dc.type | Article | en_US |
