dc.contributor.author | Asker, Erol | |
dc.contributor.author | Uzkara, Ece | |
dc.contributor.author | Zeybek, Orhan | |
dc.date.accessioned | 2019-10-16T11:34:30Z | |
dc.date.available | 2019-10-16T11:34:30Z | |
dc.date.issued | 2011 | en_US |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://doi.org/ 10.1016/j.saa.2011.05.047 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12462/7130 | |
dc.description.abstract | Series of 1,n-dicarbazolylalkanes and 1,n-di(3-methylcarbazolyl)alkanes (where n=1-5) were synthesized and the molar extinction coefficients, equilibrium constants, enthalpies, and entropies of their charge-transfer (CT) complexes with the pi-acceptors p-chloranil, tetracyanoethylene, and tetracyanoquinodimethane were investigated. 1,n-Di(3-methylcarbazolyl)alkanes formed CT complexes with higher equilibrium constants, more negative enthalpies and entropies than 1,n-dicarbazolylalkanes. Vibrational spectra of CT complexes of one of the donor molecules (1.4-dicarbazolylbutane) with all three acceptors were compared. | en_US |
dc.description.sponsorship | Scientific Research Projects Unit of Balikesir University
2009/09 | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.isversionof | 10.1016/j.saa.2011.05.047 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | 1,N-Di(3-Methylcarbazolyl)Alkanes; P-Chloranil | en_US |
dc.subject | Tetracyanoethylene | en_US |
dc.subject | Tetracyanoquinodimethane | en_US |
dc.subject | CT Complexes | en_US |
dc.subject | Enthalpy And Entropy of Complexation | en_US |
dc.title | Effects of methyl substituent on the charge-transfer complexations of dicarbazolylalkanes with p-chloranil, tetracyanoethylene and tetracyanoquinodimethane | en_US |
dc.type | article | en_US |
dc.relation.journal | Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy | en_US |
dc.contributor.department | Necatibey Eğitim Fakültesi | en_US |
dc.contributor.authorID | 0000-0002-4211-7747 | en_US |
dc.identifier.volume | 79 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.startpage | 1731 | en_US |
dc.identifier.endpage | 1738 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |