dc.contributor.author | Yıldız, Cem Burak | |
dc.contributor.author | Leszczyńska, Kinga I. | |
dc.contributor.author | González-Gallardo, Sandra | |
dc.contributor.author | Zimmer, Michael | |
dc.contributor.author | Azizoğlu, Akın | |
dc.contributor.author | Biskup, Till | |
dc.contributor.author | Kay, Christopher | |
dc.contributor.author | Hüch, Volker | |
dc.contributor.author | Rzepa, Henry S. | |
dc.contributor.author | Scheschkewitz, David | |
dc.date.accessioned | 2021-03-12T07:59:09Z | |
dc.date.available | 2021-03-12T07:59:09Z | |
dc.date.issued | 2020 | en_US |
dc.identifier.issn | 1433-7851 | |
dc.identifier.issn | 1521-3773 | |
dc.identifier.uri | https://doi.org/10.1002/anie.202006283 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12462/11191 | |
dc.description | Azizoğlu, Akın (Balikesir Author) | en_US |
dc.description.abstract | Main group analogues of cyclobutane-1,3-diyls are fascinating due to their unique reactivity and electronic properties. So far only heteronuclear examples have been isolated. Here we report the isolation and characterization of all-silicon 1,3-cyclobutanediyls as stable closed-shell singlet species from the reversible reactions of cyclotrisilenec-Si(3)Tip(4)(Tip=2,4,6-triisopropylphenyl) with the N-heterocyclic silylenesc-[(CR2CH2)(NtBu)(2)]Si: (R=H or methyl) with saturated backbones. At elevated temperatures, tetrasilacyclobutenes are obtained from these equilibrium mixtures. The corresponding reaction with the unsaturated N-heterocyclic silylenec-(CH)(2)(NtBu)(2)Si: proceeds directly to the corresponding tetrasilacyclobutene without detection of the assumed 1,3-cyclobutanediyl intermediate. | en_US |
dc.description.sponsorship | Deutscher Akademischer Austausch Dienst (DAAD) | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Wiley V C H Verlag GMBH | en_US |
dc.relation.isversionof | 10.1002/anie.202006283 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Diradicaloids | en_US |
dc.subject | Low-Valent Species | en_US |
dc.subject | Silicon | en_US |
dc.subject | Small Ring | en_US |
dc.subject | Synthesis | en_US |
dc.title | Equilibrium formation of stable all-silicon versions of 1,3-cyclobutanediyl | en_US |
dc.type | article | en_US |
dc.relation.journal | Angewandte Chemie - International Edition | en_US |
dc.contributor.department | Fen Edebiyat Fakültesi | en_US |
dc.contributor.authorID | 0000-0002-5200-6004 | en_US |
dc.contributor.authorID | 0000-0003-2913-0004 | en_US |
dc.contributor.authorID | 0000-0001-5600-8034 | en_US |
dc.contributor.authorID | 0000-0002-1117-8934 | en_US |
dc.contributor.authorID | 0000-0002-0424-4673 | en_US |
dc.contributor.authorID | 0000-0002-2930-9074 | en_US |
dc.contributor.authorID | 0000-0002-5098-1842 | en_US |
dc.identifier.volume | 59 | en_US |
dc.identifier.issue | 35 | en_US |
dc.identifier.startpage | 15087 | en_US |
dc.identifier.endpage | 15092 | en_US |
dc.relation.tubitak | 2214-A | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |