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dc.contributor.authorYıldız, Cem Burak
dc.contributor.authorLeszczyńska, Kinga I.
dc.contributor.authorGonzález-Gallardo, Sandra
dc.contributor.authorZimmer, Michael
dc.contributor.authorAzizoğlu, Akın
dc.contributor.authorBiskup, Till
dc.contributor.authorKay, Christopher
dc.contributor.authorHüch, Volker
dc.contributor.authorRzepa, Henry S.
dc.contributor.authorScheschkewitz, David
dc.date.accessioned2021-03-12T07:59:09Z
dc.date.available2021-03-12T07:59:09Z
dc.date.issued2020en_US
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://doi.org/10.1002/anie.202006283
dc.identifier.urihttps://hdl.handle.net/20.500.12462/11191
dc.descriptionAzizoğlu, Akın (Balikesir Author)en_US
dc.description.abstractMain group analogues of cyclobutane-1,3-diyls are fascinating due to their unique reactivity and electronic properties. So far only heteronuclear examples have been isolated. Here we report the isolation and characterization of all-silicon 1,3-cyclobutanediyls as stable closed-shell singlet species from the reversible reactions of cyclotrisilenec-Si(3)Tip(4)(Tip=2,4,6-triisopropylphenyl) with the N-heterocyclic silylenesc-[(CR2CH2)(NtBu)(2)]Si: (R=H or methyl) with saturated backbones. At elevated temperatures, tetrasilacyclobutenes are obtained from these equilibrium mixtures. The corresponding reaction with the unsaturated N-heterocyclic silylenec-(CH)(2)(NtBu)(2)Si: proceeds directly to the corresponding tetrasilacyclobutene without detection of the assumed 1,3-cyclobutanediyl intermediate.en_US
dc.description.sponsorshipDeutscher Akademischer Austausch Dienst (DAAD)en_US
dc.language.isoengen_US
dc.publisherWiley V C H Verlag GMBHen_US
dc.relation.isversionof10.1002/anie.202006283en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectDiradicaloidsen_US
dc.subjectLow-Valent Speciesen_US
dc.subjectSiliconen_US
dc.subjectSmall Ringen_US
dc.subjectSynthesisen_US
dc.titleEquilibrium formation of stable all-silicon versions of 1,3-cyclobutanediylen_US
dc.typearticleen_US
dc.relation.journalAngewandte Chemie - International Editionen_US
dc.contributor.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorID0000-0002-5200-6004en_US
dc.contributor.authorID0000-0003-2913-0004en_US
dc.contributor.authorID0000-0001-5600-8034en_US
dc.contributor.authorID0000-0002-1117-8934en_US
dc.contributor.authorID0000-0002-0424-4673en_US
dc.contributor.authorID0000-0002-2930-9074en_US
dc.contributor.authorID0000-0002-5098-1842en_US
dc.identifier.volume59en_US
dc.identifier.issue35en_US
dc.identifier.startpage15087en_US
dc.identifier.endpage15092en_US
dc.relation.tubitak2214-A
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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