dc.contributor.author | Yardan, Alper | |
dc.contributor.author | Hopa, Çiğdem | |
dc.contributor.author | Yahşi, Yasemin | |
dc.contributor.author | Karahan, Ahmet | |
dc.contributor.author | Kara, Hülya | |
dc.contributor.author | Kurtaran, Raif | |
dc.date.accessioned | 2019-10-18T11:30:17Z | |
dc.date.available | 2019-10-18T11:30:17Z | |
dc.date.issued | 2015 | en_US |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://doi.org/10.1016/j.saa.2014.08.091 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12462/9020 | |
dc.description | Yardan, Alper (Balikesir Author) | en_US |
dc.description.abstract | Two new heterodinuclear Schiff base complexes, [Hg(L)NiCl2(DMF)(2)] 1, and [Zn(L)NiCl2(DMF)(2)] 2, where H2L = N,N'-bis(salicylidene)-1,3-diaminopropane and DMF = dimethylformamide have been synthesized and characterized using elemental analysis, IR spectroscopy, thermal analysis and X-ray diffraction. Structural studies on 1 and 2 reveal the presence of a heterodinuclear [(NiHgII)-Hg-II] unit and [(ZnNiII)-Ni-II] in which the central metal ions are connected to each other by two phenolate oxygen bridges. For complex 1 the Ni(II) ion adopts an elongated octahedral geometry (NiN2O4) while the Hg(II) ion assumes a distorted tetrahedral arrangement (HgO2Cl2) whereas for complex 2 the Zn(II) ion adopts an elongated octahedral geometry (ZnN2O4) while the Ni(II) ion assumes a distorted tetrahedral arrangement (NiO2Cl2). There are intermolecular C-H center dot center dot center dot Cl-M interactions among the dinuclear complexes which are interconnected for 1 and 2. These intermolecular interactions result in the formation of a three dimensional structure for 1 and one dimensional zig-zag chains for 2. | en_US |
dc.description.sponsorship | Balikesir University - 2007/10 | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.isversionof | 10.1016/j.saa.2014.08.091 | en_US |
dc.rights | info:eu-repo/semantics/embargoedAccess | en_US |
dc.subject | Schiff Bases | en_US |
dc.subject | Heterodinuclear Complexes | en_US |
dc.subject | Phenoxo Bridge | en_US |
dc.subject | Thermal Analysis | en_US |
dc.subject | Single Crystal X-Ray | en_US |
dc.title | Two new heterodinuclear schiff base complexes: synthesis, crystal structure and thermal studies | en_US |
dc.type | article | en_US |
dc.relation.journal | Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy | en_US |
dc.contributor.department | Fen Edebiyat Fakültesi | en_US |
dc.contributor.authorID | 0000-0001-6916-831X | en_US |
dc.contributor.authorID | 0000-0002-2032-8930 | en_US |
dc.contributor.authorID | 0000-0001-6916-831X | en_US |
dc.identifier.volume | 137 | en_US |
dc.identifier.startpage | 351 | en_US |
dc.identifier.endpage | 356 | en_US |
dc.relation.tubitak | info:eu-repo/grantAgreement/TUBITAK/TBAG-108T431 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |