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dc.contributor.authorYardan, Alper
dc.contributor.authorHopa, Çiğdem
dc.contributor.authorYahşi, Yasemin
dc.contributor.authorKarahan, Ahmet
dc.contributor.authorKara, Hülya
dc.contributor.authorKurtaran, Raif
dc.date.accessioned2019-10-18T11:30:17Z
dc.date.available2019-10-18T11:30:17Z
dc.date.issued2015en_US
dc.identifier.issn1386-1425
dc.identifier.urihttps://doi.org/10.1016/j.saa.2014.08.091
dc.identifier.urihttps://hdl.handle.net/20.500.12462/9020
dc.descriptionYardan, Alper (Balikesir Author)en_US
dc.description.abstractTwo new heterodinuclear Schiff base complexes, [Hg(L)NiCl2(DMF)(2)] 1, and [Zn(L)NiCl2(DMF)(2)] 2, where H2L = N,N'-bis(salicylidene)-1,3-diaminopropane and DMF = dimethylformamide have been synthesized and characterized using elemental analysis, IR spectroscopy, thermal analysis and X-ray diffraction. Structural studies on 1 and 2 reveal the presence of a heterodinuclear [(NiHgII)-Hg-II] unit and [(ZnNiII)-Ni-II] in which the central metal ions are connected to each other by two phenolate oxygen bridges. For complex 1 the Ni(II) ion adopts an elongated octahedral geometry (NiN2O4) while the Hg(II) ion assumes a distorted tetrahedral arrangement (HgO2Cl2) whereas for complex 2 the Zn(II) ion adopts an elongated octahedral geometry (ZnN2O4) while the Ni(II) ion assumes a distorted tetrahedral arrangement (NiO2Cl2). There are intermolecular C-H center dot center dot center dot Cl-M interactions among the dinuclear complexes which are interconnected for 1 and 2. These intermolecular interactions result in the formation of a three dimensional structure for 1 and one dimensional zig-zag chains for 2.en_US
dc.description.sponsorshipBalikesir University - 2007/10en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.isversionof10.1016/j.saa.2014.08.091en_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.subjectSchiff Basesen_US
dc.subjectHeterodinuclear Complexesen_US
dc.subjectPhenoxo Bridgeen_US
dc.subjectThermal Analysisen_US
dc.subjectSingle Crystal X-Rayen_US
dc.titleTwo new heterodinuclear schiff base complexes: synthesis, crystal structure and thermal studiesen_US
dc.typearticleen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.contributor.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorID0000-0001-6916-831Xen_US
dc.contributor.authorID0000-0002-2032-8930en_US
dc.contributor.authorID0000-0001-6916-831Xen_US
dc.identifier.volume137en_US
dc.identifier.startpage351en_US
dc.identifier.endpage356en_US
dc.relation.tubitakinfo:eu-repo/grantAgreement/TUBITAK/TBAG-108T431en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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