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Designing antiferromagnetically coupled mono-, di- and tri-bridged copper(ii)-based catecholase models by varying the 'Auxiliary Parts' of the ligand and anionic co-ligand
Dasgupta, Sanchari; Chakraborty, Prateeti; Kundu, Priyanka; Kara, Hülya; Aullon, Gabriel; Zangrando, Ennio; Das, Debasis (Royal Soc Chemistry, 2019)Three Schiff base ligands were synthesized via condensation between 2,6-diformyl-4-R-phenol [where R = tert-butyl (HL1), iso-propyl (HL2), and chloro (HL3)] and N,N-dimethylethylene-1,2-diamine to prepare a series of ... -
Role of electronegative atom present on ligand backbone and substrate binding mode on catecholase- and phosphatase-like activities of dinuclear ni-ıı complexes: a theoretical support
Adhikary, Jaydeep; Majumdar, Ishani; Kundu, Priyanka; Kornweitz, Haya; Kara, Hülya; Das, Debasis (Wiley-V C H Verlag GMBH, 2018)The reaction of two pentadentate compartmental ligands HL1 and HL2 [HL1 = 2,6-bis((E)-(2-morpholinoethylimino)methyl)-4-tert-butylphenol; HL2 = 2,6-bis((E)-(2-(piperidin-1-yl)ethylimino)methyl)-4-tert-butylphenol] with ...