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Reductive cleavage of carbon monoxide by a disilenide
Majumdar, Moumita; Omlor, Isabell; Yıldız, Cem Burak; Azizoğlu, Akın; Huch, Volker; Scheschkewitz, David (Wiley-v c h verlag gmbh, 2015)The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The CC-coupled product can be regarded as a silanone dimer with pending alkyne and silirene ...